Insights from swirl number and ambient pressure variations with a hydrogen/ammonia swirl stabilized diffusion flame

Vivoli, Robin, Goktepe, Burak, Pugh, Daniel ORCID: https://orcid.org/0000-0002-6721-2265, Morris, Steven ORCID: https://orcid.org/0000-0001-5865-8911, Bowen, Phil and Valera-Medina, Agustin ORCID: https://orcid.org/0000-0003-1580-7133 2025. Insights from swirl number and ambient pressure variations with a hydrogen/ammonia swirl stabilized diffusion flame. International Journal of Hydrogen Energy 190 , 151941. 10.1016/j.ijhydene.2025.151941

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Abstract

Contemporary research into decarbonized fuels such as H2/NH3 has highlighted complex challenges with applied combustion, with marked changes in thermochemical properties leading to significant issues such as limited operational range, flashback, and instability, particularly when attempts are made to optimize emissions production in conventional lean-premixed systems. Non-premixed configurations may address some of these issues but often lead to elevated NOx production, particularly when ammonia is retained in the fuel mixture. Optimized fuel injection and blending strategies are essential to mitigate these challenges. This study investigates the application of a 75 %/25 %mol H2/NH3 blend in a swirl-stabilized combustor, operated at elevated conditions of inlet temperature (500 K) and ambient pressure (0.11–0.6 MPa). A complex, nonmonotonic relationship between swirl number and increasing ambient combustor pressure is demonstrated, highlighting the intricate interplay between swirling flow structures and reaction kinetics, which remains poorly understood. At medium swirl (SN = 0.8) an increase in pressure initially reduces NO emissions, diminishing past ∼0.3 MPa, with an opposing trend evident for high swirl (SN = 2.0) as NO emissions fall rapidly when combustor pressure approaches 0.6 MPa. High-fidelity numerical modeling is presented to elucidate these interactions in detail. Numerical data, generated using Detached Eddy Simulations (DES), were validated against experimental results to demonstrate a change in flame anchoring on the axial shear layer and marked change in recirculated flow structure, successfully capturing the features of higher swirl number flows. Favorable comparisons are made with optical data and a reduction in NO emissions with increasing pressure is demonstrated to replicate changes to the swirling flame chemical kinetics. Findings provide valuable insights into the combustion behavior of hydrogen-rich ammonia flames, contributing to the development of cleaner combustion technologies.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Engineering
Publisher:	Elsevier
ISSN:	0360-3199
Date of First Compliant Deposit:	3 November 2025
Date of Acceptance:	8 October 2025
Last Modified:	03 Nov 2025 14:45
URI:	https://orca.cardiff.ac.uk/id/eprint/182074

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