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Reuse of oxidatively remediated petroleum-contaminated soil as flowable fill: Solidification mechanisms and performance evaluation

Wei, Wei, Wei, Mingli, Wei, Yifan, Yin, Fei, Zhao, Ying, Zhang, Tingting and Jin, Fei ORCID: https://orcid.org/0000-0003-0899-7063 2026. Reuse of oxidatively remediated petroleum-contaminated soil as flowable fill: Solidification mechanisms and performance evaluation. Journal of Cleaner Production 568 , 148659. 10.1016/j.jclepro.2026.148659

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Abstract

This study developed a flowable fill using oxidatively remediated petroleum-contaminated soil stabilized with cement and bentonite. The fluidity, strength, permeability, durability, leaching behavior, and microstructural characteristics of the material were systematically evaluated. Results showed that a cement-to-bentonite ratio of 5:4 and a binder dosage of 10-15% yielded suitable fluidity (140-200 mm). After 14 days of curing, the solidified specimens met the key engineering criteria for subgrade backfill, with an unconfined compressive strength exceeding 0.80 MPa and a hydraulic conductivity below 1 × 10−7 cm/s. Mineralogical and microstructural analyses revealed that hydration products (C-S-H/C-A-S-H) effectively improved the soil fabric, whereas residual oxidants and hydrocarbons in the remediated soil led to a slightly more porous structure and marginally lower mechanical performance than that of the solidified virgin soil. Supplementary tests using natural soil confirmed that the optimized cement-bentonite formulation remained applicable under more realistic soil conditions. TCLP results further showed low leaching concentrations of extractable petroleum hydrocarbons (C10-C40) and dissolved Fe, while hydrogen peroxide was not detected in the leachates of remediated-soil-based specimens. In addition, the solidified material showed good durability under wetting-drying cycles, maintaining structural integrity and acceptable performance. This study provides a practical waste-to-resource pathway that can reduce the disposal burden of remediated soil while decreasing the demand for virgin construction materials.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Schools > Engineering
Additional Information: RRS policy applied
Publisher: Elsevier
ISSN: 0959-6526
Date of First Compliant Deposit: 22 June 2026
Date of Acceptance: 31 May 2026
Last Modified: 22 Jun 2026 08:30
URI: https://orca.cardiff.ac.uk/id/eprint/187610

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