Diisobutylaluminium phenyl selenide

Maruoka, Keiji, Yamamoto, Hisashi, Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 and Khan, Zulfiqar Ali 2008. Diisobutylaluminium phenyl selenide. Paquette, Leo A., ed. e-EROS encyclopedia of reagents for organic synthesis, Chichester: Wiley,

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Abstract

[85028-55-3] C14H23AlSe (MW 297.28) InChI = 1S/C6H6Se.2C4H9.Al/c7-6-4-2-1-3-5-6;2*1-4(2)3;/h1-5,7H;2*4H,1H2,2-3H3;/q;;;+1/p-1 InChIKey = ISUTVHLAWSJJPV-UHFFFAOYSA-M (phenylselenylation agent for Beckmann rearrangement of oxime sulfonates,1, 2 acetal cleavage,4, 5 and epoxide opening6) Solubility: sol toluene, CH2Cl2, hexane. Form Supplied in: prepared in situ from commercially available reagents. Preparative Methods: by addition of Diphenyl Diselenide (1 equiv) to a 1 M hexane solution of Diisobutylaluminum Hydride (2 equiv) in CH2Cl2 at 0 °C for 30 min.1 Handling, Storage, and Precautions: use in a fume hood; the dry solid and solutions are highly flammable and must be handled in the absence of oxygen and moisture; the solution should be used as prepared for best results.

Item Type:	Book Section
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Additional Information:	DOI for book 10.1002/047084289X.rd247.pub2
Publisher:	Wiley
Related URLs:	http://onlinelibrary.wiley.com/o/eros/ar...
Last Modified:	20 Oct 2022 07:50
URI:	https://orca.cardiff.ac.uk/id/eprint/26561

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