Synthesis and luminescence properties of dinuclear lanthanide complexes derived from covalently linked macrocyclic ligands

Pope, Simon J. A. ORCID: https://orcid.org/0000-0001-9110-9711, Kenwright, Alan M., Boote, Valerie A. and Faulkner, Stephen 2003. Synthesis and luminescence properties of dinuclear lanthanide complexes derived from covalently linked macrocyclic ligands. Dalton Transactions 2003 (19) , pp. 3780-3784. 10.1039/b309115e

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Abstract

A series of homo-binuclear lanthanide complexes have been prepared from DO3A derived systems containing seven-coordinate binding domains linked via an aromatic. The luminescence properties of xylyl bridged complexes show that the lanthanide ions behave as isolated centres, while the combination of the lanthanide contraction and the lipophilicity of the linker group limits inner-sphere hydration around the metal centres for later lanthanides such as ytterbium.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	RSC
ISSN:	1477-9226
Last Modified:	21 Oct 2022 10:53
URI:	https://orca.cardiff.ac.uk/id/eprint/41647

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