Comparison of the FT Raman spectra of inorganic tetrahedral ions over the temperature range 77 to 473 K

Pope, Simon J. A. ORCID: https://orcid.org/0000-0001-9110-9711 and West, Yvonne D. 1995. Comparison of the FT Raman spectra of inorganic tetrahedral ions over the temperature range 77 to 473 K. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 51 (12) , pp. 2027-2037. 10.1016/0584-8539(95)01509-1

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Abstract

The vibrational spectra recorded over a wide temperature range (77–473 K) of a number of inorganic transition metal salts containing tetraoxyanions in both solution and crystal phases are reported. All modes in these cases are Raman active and the bands predicted by site-symmetry analysis are observed. Only bands assigned as ν3 and ν1 are found to be temperature dependent. The significance of this is discussed.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Elsevier
ISSN:	1386-1425
Last Modified:	21 Oct 2022 10:54
URI:	https://orca.cardiff.ac.uk/id/eprint/41659

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