Redshaw, C., Wilkinson, Geoffrey, Sweet, Tracy ORCID: https://orcid.org/0000-0002-6947-5018 and Hursthouse, Michael B. 1993. Synthesis and x-ray crystal-structure of the organotungsten(v) o-phenylene diamido complex, (eta-c5me5)wcl2(1,2-(hn)2c6h4). Polyhedron 12 (19) , pp. 2417-2420. |
Abstract
The paramagnetic tungsten(V) complex CpWCl2[1,2-(HN)2C6H4], CP* = C5Me5, has been obtained by interaction of CpWCl4 with o-phenylenediamine (1,2-diaminobenzene, o-pdaH-2). The X-ray crystal structure shows apseudo-square pyramidal geometry with the chelating diamido group andchlorine atoms forming the base and a slipped (3e) Cp group occupying the axial site.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Engineering |
Subjects: | Q Science > QD Chemistry |
Publisher: | Elsevier |
Last Modified: | 24 Oct 2022 10:19 |
URI: | https://orca.cardiff.ac.uk/id/eprint/43889 |
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