Synthesis and x-ray crystal-structure of the organotungsten(v) o-phenylene diamido complex, (eta-c5me5)wcl2(1,2-(hn)2c6h4)

Redshaw, C., Wilkinson, Geoffrey, Sweet, Tracy ORCID: https://orcid.org/0000-0002-6947-5018 and Hursthouse, Michael B. 1993. Synthesis and x-ray crystal-structure of the organotungsten(v) o-phenylene diamido complex, (eta-c5me5)wcl2(1,2-(hn)2c6h4). Polyhedron 12 (19) , pp. 2417-2420.

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Abstract

The paramagnetic tungsten(V) complex CpWCl2[1,2-(HN)2C6H4], CP* = C5Me5, has been obtained by interaction of CpWCl4 with o-phenylenediamine (1,2-diaminobenzene, o-pdaH-2). The X-ray crystal structure shows apseudo-square pyramidal geometry with the chelating diamido group andchlorine atoms forming the base and a slipped (3e) Cp group occupying the axial site.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Engineering
Subjects:	Q Science > QD Chemistry
Publisher:	Elsevier
Last Modified:	24 Oct 2022 10:19
URI:	https://orca.cardiff.ac.uk/id/eprint/43889

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