Williams, I., Kariuki, Benson ORCID: https://orcid.org/0000-0002-8658-3897, Reeves, K. and Cox, Liam R. 2006. Stereoselective synthesis of 2-dienyl-substituted pyrrolidines using an eta(4)-dienetricarbonyliron complex as the stereodirecting element: Elaboration to the pyrrolizidine skeleton. Organic Letters 8 (20) , pp. 4389-4392. 10.1021/ol061132l |
Official URL: http://pubs.acs.org/doi/abs/10.1021/ol061132l
Abstract
Primary amines react with keto-aldehyde functionality located in the side-chain of an η4-dienetricarbonyliron complex to provide the corresponding pyrrolidines in excellent diastereoselectivity. Two of the pyrrolidine products, 1i and 1k, have been elaborated into pyrrolizidines using a 1,5-C−H insertion and radical cyclization strategy, respectively.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Publisher: | American Chemical Society |
ISSN: | 1523-7060 |
Last Modified: | 24 Oct 2022 11:11 |
URI: | https://orca.cardiff.ac.uk/id/eprint/47240 |
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