Stereoselective rearrangements with chiral hypervalent iodine reagents

Farid, Umar, Malmedy, Florence, Claveau, Romain, Albers, Lena and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2013. Stereoselective rearrangements with chiral hypervalent iodine reagents. Angewandte Chemie - International Edition 52 (27) , pp. 7018-7022. 10.1002/anie.201302358

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Abstract

I likes rearrangements: Hypervalent iodine compounds can be used as environmentally friendly, mild, and selective reagents for highly enantioselective rearrangements of alkenes. For the first time, rearrangements to α-arylated ketones can be performed enantioselectively using lactic acid-based iodine(III) reagents.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	acetals; aryl migration; hypervalent iodine; rearrangement; stereoselective synthesis
Publisher:	Wiley-Blackwell
ISSN:	1433-7851
Last Modified:	10 Nov 2023 12:46
URI:	https://orca.cardiff.ac.uk/id/eprint/48529

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