Albonetti, Stefania, Pasini, Thomas, Lolli, Alice, Blosi, Magda, Piccinini, Marco ![]() ![]() ![]() ![]() |
Official URL: http://dx.doi.org/10.1016/j.cattod.2012.05.039
Abstract
5-Hydroxymethyl-2-furfural (HMF) oxidation to furandicarboxylic acid (FDCA) was performed under mild reaction conditions using TiO 2-supported Au and Au-Cu catalysts synthesized from pre-formed nanoparticles of different composition. Catalysts were characterized by BET, XRD and XPS. The Au 3Cu 1/TiO 2 catalyst exhibited the best catalytic performance for FDCA yield. Moreover, after reaction, bimetallic Au-Cu catalysts with high gold content can be recovered by filtration and reused without significant loss of activity and selectivity; whereas, the monometallic gold materials are not stable.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Cardiff Catalysis Institute (CCI) Chemistry |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | 2,5-Furandicarboxylic acid; Gold-copper catalysts; Preformed nanoparticles; Selective oxidation of HMF |
Publisher: | Elsevier |
ISSN: | 0920-5861 |
Last Modified: | 25 Oct 2022 08:27 |
URI: | https://orca.cardiff.ac.uk/id/eprint/53061 |
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