Bifunctional ZnIILnIII dinuclear complexes combining field induced SMM behavior and luminescence: enhanced NIR lanthanide emission by 9-anthracene carboxylate bridging ligands

Palacios, María A., Titos-Padilla, Silvia, Ruiz, José, Herrera, Juan Manuel, Pope, Simon J. A. ORCID: https://orcid.org/0000-0001-9110-9711, Brechin, Euan K. and Colacio, Enrique 2014. Bifunctional ZnIILnIII dinuclear complexes combining field induced SMM behavior and luminescence: enhanced NIR lanthanide emission by 9-anthracene carboxylate bridging ligands. Inorganic Chemistry 53 (3) , pp. 1465-1474. 10.1021/ic402597s

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Abstract

A series of ZnIILnIII dinuclear complexes of formula [Zn(μ-L)(μ-X)Ln(NO3)2] (H2L = compartmental ligand; X = none, NO3−, OAc−, and 9-An; LnIII = Dy, Tb, Er, Nd, Yb) having double diphenoxo bridges and triple diphenoxonitrate, acetate, and 9-anthracene carboxylate bridges have been structurally and magnetically characterized, and their luminescent properties studied in the vis and NIR regions. Two DyIII complexes and two ErIII complexes combine field-induced SMM behavior and luminescent properties.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	0020-1669
Last Modified:	25 Oct 2022 09:21
URI:	https://orca.cardiff.ac.uk/id/eprint/58146

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