Kinetics of iminium ion catalysis

Evans, Gareth James, Gibbs, Timothy John, Jenkins, Robert Leyshon, Coles, Simon J., Hursthouse, Michale B., Platts, James Alexis ORCID: https://orcid.org/0000-0002-1008-6595 and Tomkinson, Nicholas Charles Oliver 2008. Kinetics of iminium ion catalysis. Angewandte Chemie. International Edition 47 (15) , pp. 2820-2823. 10.1002/anie.200705539

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Abstract

Identifying the bottleneck: Kinetic and computational data for the key steps of the iminium ion catalyzed Diels–Alder reaction show that the cycloaddition (step II in scheme) is the rate-determining step of the catalytic cycle and provide a rationale for developing more-active catalyst architectures.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Uncontrolled Keywords:	cycloaddition ; Density functional calculations ; Iminium ions ; Kinetics ; Organocatalysis
Publisher:	Wiley
ISSN:	1433-7851
Last Modified:	17 Oct 2022 09:51
URI:	https://orca.cardiff.ac.uk/id/eprint/5934

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