Synthesis of Indene Derivatives via Electrophilic Cyclization

Khan, Zulfiqar Ali and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2009. Synthesis of Indene Derivatives via Electrophilic Cyclization. Organic Letters 11 (1) , pp. 229-231. 10.1021/ol8024956

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Abstract

3-Iodo-1H-indene derivatives are synthesized by iodonium-promoted 5-endo-dig carbocyclization of 2-substituted ethynylmalonates. Various 2-substituted ethynylmalonates bearing aryl-, alkyl- and ether-protected propargyl alcohols were successfully converted to cyclized products. Their use in subsequent reactions as substrate and catalyst was investigated.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	1523-7060
Last Modified:	17 Oct 2022 09:53
URI:	https://orca.cardiff.ac.uk/id/eprint/6032

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