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Synthesis of Indene Derivatives via Electrophilic Cyclization

Khan, Zulfiqar Ali and Wirth, Thomas 2009. Synthesis of Indene Derivatives via Electrophilic Cyclization. Organic Letters 11 (1) , pp. 229-231. 10.1021/ol8024956

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3-Iodo-1H-indene derivatives are synthesized by iodonium-promoted 5-endo-dig carbocyclization of 2-substituted ethynylmalonates. Various 2-substituted ethynylmalonates bearing aryl-, alkyl- and ether-protected propargyl alcohols were successfully converted to cyclized products. Their use in subsequent reactions as substrate and catalyst was investigated.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 1523-7060
Last Modified: 04 Jun 2017 01:55

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