Hypervalent iodine-catalyzed oxidative functionalizations including stereoselective reactions

Singh, Fateh Veer and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2014. Hypervalent iodine-catalyzed oxidative functionalizations including stereoselective reactions. Chemistry - An Asian Journal 9 (4) , pp. 950-971. 10.1002/asia.201301582

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Abstract

Hypervalent iodine chemistry is now a well-established area of organic chemistry. Novel hypervalent iodine reagents have been introduced in many different transformations owing to their mild reaction conditions and environmentally friendly nature. Recently, these reagents have received particular attention because of their applications in catalysis. Numerous hypervalent iodine-catalyzed oxidative functionalizations such as oxidations of various alcohols and phenols, α-functionalizations of carbonyl compounds, cyclizations, and rearrangements have been developed successfully. In these catalytic reactions stoichiometric oxidants such as mCPBA or oxone play a crucial role to generate the iodine(III) or iodine(V) species in situ. In this Focus Review, recent developments of hypervalent iodine-catalyzed reactions are described including some asymmetric variants. Catalytic reactions using recyclable hypervalent iodine catalysts are also covered.

Item Type:	Article
Date Type:	Published Online
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Additional Information:	Catalytic oxidations; hypervalent iodine; oxidants; rearrangement; stereoselective reactions.
Publisher:	Wiley-Blackwell
ISSN:	1861-4728
Last Modified:	27 Oct 2022 08:52
URI:	https://orca.cardiff.ac.uk/id/eprint/63614

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