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Cycloaddition reactions between dicyclohexylboron azide and alkynes

Melen, Rebecca L. and Stephan, Douglas W. 2013. Cycloaddition reactions between dicyclohexylboron azide and alkynes. Dalton Transactions 42 (14) , pp. 4795-4798. 10.1039/c3dt00068k

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The room temperature 1,3-dipolar cycloaddition reactions of the boron azide, Cy2BN3 with the electron-poor acetylenes RCO2CCCO2R, EtCCCOMe and HCCP(O)Ph2 afforded new 1,2,3-triazoles. In the case of RCO2CCCO2R, a new macrocyclic product was isolated with loss of the R group.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1477-9226
Date of Acceptance: 11 February 2013
Last Modified: 04 Jun 2017 06:49

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