Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831, McPartlin, Mary and Wright, Dominic S.
2011.
An unexpected dependence on the SnII base; reactions of Sn(NR2)2 with aromatic dithiols.
Dalton Transactions
40
(8)
, pp. 1649-1651.
10.1039/c0dt01690j
|
Official URL: http://dx.doi.org/10.1039/c0dt01690j
Abstract
Unexpectedly, the reactions of the SnII base Sn(NMe2)2 with 1,2-benzodithiols [L(SH)2] do not give the stannylenes, L(S)2Sn, which are generated with Sn{N(SiMe3)2}2, instead the ion-separated SnIV compounds [Sn{L(S)2}]2−2[R2NH2]+ are formed in high yields.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Chemistry |
| Subjects: | Q Science > QD Chemistry |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1477-9226 |
| Date of Acceptance: | 5 January 2011 |
| Last Modified: | 27 Oct 2022 09:16 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/65052 |
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