Formation of N-bridgehead 1,2,5-thiadiazolium and selenadiazolium rings through an intramolecular cyclisation reaction

Bacon, Catherine E., Eisler, Dana J., Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831 and Rawson, Jeremy M. 2008. Formation of N-bridgehead 1,2,5-thiadiazolium and selenadiazolium rings through an intramolecular cyclisation reaction. Chemical Communications 40 , pp. 4924-4926. 10.1039/b809987a

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Abstract

Treatment of N-lithiopyridylketimide derivatives Li[R(C = N)py] (R = Ph, py) with ECl2 (E = S, Se) affords the fused thiadiazolium and selenadiazolium salts [RC6H4N2E]Cl [1]Cl and [2]Cl containing a bridgehead N atom through intramolecular coordination.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	RSC Publishing
ISSN:	1359-7345
Date of Acceptance:	11 August 2008
Last Modified:	27 Oct 2022 09:16
URI:	https://orca.cardiff.ac.uk/id/eprint/65059

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