The Effect of Cr, Ni, Fe, and Mn Dopants on the Performance of Hydrothermal Synthesized Vanadium Phosphate Catalysts for n-Butane Oxidation

Taufiq-Yap, Yun, Theam, K. L., Hutchings, Graham John ORCID: https://orcid.org/0000-0001-8885-1560, Dummer, Nicholas ORCID: https://orcid.org/0000-0002-0946-6304 and Bartley, Jonathan Keith ORCID: https://orcid.org/0000-0003-4640-541X 2010. The Effect of Cr, Ni, Fe, and Mn Dopants on the Performance of Hydrothermal Synthesized Vanadium Phosphate Catalysts for n-Butane Oxidation. Petroleum Science and Technology 28 (10) , pp. 997-1012. 10.1080/10916460903058004

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Abstract

Vanadium phosphorus oxide (VPO) catalysts synthesized via hydrothermal method were introduced with some different dopants, Cr, Ni, Fe, and Mn during the preparation of the precursors, VOHPO4 · 0.5H2O. All modified precursors were subsequently transformed under reaction conditions to give the active phase, (VO)2P2O7. Several techniques were used to characterize the physicochemical properties of the catalysts, such as X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), H2-temperature programmed reduction (TPR), laser Raman spectroscopy (LRS), and chemical analysis. The catalytic performance of the catalysts for selective oxidation of n-butane to maleic anhydride has been carried out by using a fixed bed microreactor (673 K, gas hourly space velocity [GHSV] = 2,400 hr-1). The results show that the addition of dopants into the VPO catalysts increased the surface area of the catalysts and induced the formation of V5+ phases as shown in XRD and LRS spectra that promoted the catalytic performance. A further water reflux treatment to all the precursors gave catalysts with only (VO)2P2O7 phase. However, the activity and selectivity of these catalysts were reduced markedly.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry Research Institutes & Centres > Cardiff Catalysis Institute (CCI)
Subjects:	Q Science > QD Chemistry
Publisher:	Taylor & Francis
ISSN:	1091-6466
Last Modified:	17 Oct 2022 10:07
URI:	https://orca.cardiff.ac.uk/id/eprint/6855

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