An investigation of the effect of the addition of tin to %Pd/TiO2 for the hydrogenation of furfuryl alcohol

King, Gavin Morgan, Iqbal, Sarwat, Miedziak, Peter John, Brett, Gemma Louise, Kondrat, Simon A., Yeo, Benjamin Roy, Liu, Xi, Edwards, Jennifer Kelly ORCID: https://orcid.org/0000-0003-4089-2827, Morgan, David John ORCID: https://orcid.org/0000-0002-6571-5731, Knight, David K. and Hutchings, Graham John ORCID: https://orcid.org/0000-0001-8885-1560 2015. An investigation of the effect of the addition of tin to %Pd/TiO2 for the hydrogenation of furfuryl alcohol. ChemCatChem 7 (14) , pp. 2122-2129. 10.1002/cctc.201500242

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Abstract

The selective hydrogenation of furfuryl alcohol was investigated at room temperature by using supported palladium catalysts. The catalysts are very selective to the formation of 2-methylfuran. Furthermore, the addition of tin to palladium showed similar catalytic activity, but was more selective to tetrahydrofurfuryl alcohol. Variation of the Sn/Pd ratio has shown a considerable and interesting effect on the selectivity pattern. Addition of a small amount of Sn (1 wt %) shifted the selectivity towards tetrahydrofurfuryl alcohol and methyltetrahydrofuran, which are ring-saturated molecules. Increasing the tin ratio further decreased the catalytic activity and also showed very poor selectivity to either of these products.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Wiley
ISSN:	1867-3880
Last Modified:	01 Nov 2022 09:22
URI:	https://orca.cardiff.ac.uk/id/eprint/87747

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