Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2001. IBX - New reactions with an old reagent. Angewandte Chemie - International Edition 40 (15) , pp. 2812-2814. 10.1002/1521-3773(20010803)40:15<2812::AID-ANIE2812>3.0.CO;2-X |
Abstract
A single-electron transfer (SET) is the key step in new reactions using the hypervalent iodine compound 2-iodoxybenzoic acid (IBX) 1 as a reagent. Efficient oxidations of alcohols, oxidation of the benzylic position, or introduction of ,β-double bonds into carbonyl compounds are other new applications of this reagent.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | hypervalent compounds; iodine reagents; oxidation; radicals |
Publisher: | Wiley-Blackwell |
ISSN: | 1433-7851 |
Last Modified: | 18 Oct 2022 12:25 |
URI: | https://orca.cardiff.ac.uk/id/eprint/9759 |
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