A versatile and highly reactive polyfluorinated hypervalent iodine(III) compound

Schäfer, Sascha and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2010. A versatile and highly reactive polyfluorinated hypervalent iodine(III) compound. Angewandte Chemie. International Edition 49 (15) , pp. 2786-2789. 10.1002/anie.200907134

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Abstract

Hyper-reactive: A highly reactive, fully fluorinated hypervalent iodine reagent (see formula) mediates new transformations (e.g. the one-pot conversion of sulfides to sulfoximines) and serves as a stoichiometric oxidant in well-established reactions (e.g. C–C bond cleavage and the conversion of alcohols into aldehydes).

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	fluorine; homogeneous catalysis; hypervalent compounds; iodine; kinetics
Additional Information:	There is a German version of this article in Angewandte Chemie, 2010, vol. 122, no. 15, pp. 2846-2850: Schafer, S. and Wirth, T. (2010) 'Eine praktische und hochreaktive polyfluorierte hypervalente Iod(111)-Verbindung'. Angewandte Chemie, 122 (15), pp. 2846-2850. ISSN 1521-3757. (10.1002/ange.200907134 )
Publisher:	Wiley-Blackwell
ISSN:	1433-7851
Last Modified:	18 Oct 2022 12:25
URI:	https://orca.cardiff.ac.uk/id/eprint/9791

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