Cao, Qun ![]() ![]() ![]() |
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Official URL: http://dx.doi.org/10.1002/anie.201806480
Abstract
A form independent activation of zinc, concomitant generation of organozinc species and engagement in a Negishi cross‐coupling reaction via mechanochemical methods is reported. The reported method exhibits a broad substrate scope for both C(sp3)–C(sp2) and C(sp2)–C(sp2) couplings and is tolerant to many important functional groups. The method may offer broad reaching opportunities for the in situ generation organometallic compounds from base metals and their concomitant engagement in synthetic reactions via mechanochemical methods.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Publisher: | Wiley |
ISSN: | 1433-7851 |
Funders: | EPSRC |
Date of First Compliant Deposit: | 25 September 2018 |
Date of Acceptance: | 6 July 2018 |
Last Modified: | 05 May 2023 02:40 |
URI: | https://orca.cardiff.ac.uk/id/eprint/115231 |
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