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Ammonia storage by reversible host-guest site exchange in a robust metal-organic framework

Godfrey, Harry G. W., da Silva, Ivan, Briggs, Lydia, Carter, Joseph H., Morris, Christopher G., Savage, Mathew, Easun, Timothy L., Manuel, Pascal, Murray, Claire A., Tang, Chiu C., Frogley, Mark D., Cinque, Gianfelice, Yang, Sihai and Schröder, Martin 2018. Ammonia storage by reversible host-guest site exchange in a robust metal-organic framework. Angewandte Chemie International Edition 57 (45) , pp. 14778-14781. 10.1002/anie.201808316

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MFM‐300(Al) shows reversible uptake of NH3 (15.7 mmol g−1 at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm−3 at 293 K. In situ neutron powder diffraction and synchrotron FTIR micro‐spectroscopy on ND3@MFM‐300(Al) confirms reversible H/D site exchange between the adsorbent and adsorbate, representing a new type of adsorption interaction.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Wiley
ISSN: 1433-7851
Funders: EPSRC, ERC, Royal Society and University of Manchester
Date of First Compliant Deposit: 23 October 2018
Date of Acceptance: 11 August 2018
Last Modified: 03 Feb 2020 15:15

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