Galaverna, Renan, Fernandes, Lucas P., Browne, Duncan L. ![]() |
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Abstract
We report the development of a continuous flow approach for the preparation of two bio-derived monomer libraries. A small range of terpenes (ocimene, myrcene, α-terpinene, α-phellandrene, isoprene, and farnesene) have been used as the base set for the library, with the first library derived from a Diels–Alder reaction with the platform chemical maleic anhydride. The second library requires the derivatization of the first through a hydrogenation reaction. The potential for scale-up of both libraries has been demonstrated, with the Diels–Alder process delivering 10.5 grams of the product in 3 hours and the hydrogenation process delivering 10 grams of the material in 16 hours.
Item Type: | Article |
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Date Type: | Published Online |
Status: | Published |
Schools: | Chemistry |
Publisher: | Royal Society of Chemistry |
ISSN: | 2058-9883 |
Date of First Compliant Deposit: | 20 February 2019 |
Date of Acceptance: | 23 November 2018 |
Last Modified: | 01 Dec 2024 03:15 |
URI: | https://orca.cardiff.ac.uk/id/eprint/119749 |
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