Sawicki, Marcin, Kwok, Angela, Tredwell, Matthew ![]() |
Official URL: https://doi.org/10.1186/1860-5397-3-34
Abstract
Acyclic allylic monofluorides were prepared by electrophilic fluorination of branched (E)-allylsilanes with Selectfluor. These reactions proceeded with efficient transfer of chirality from the silylated to the fluorinated stereocentre. Upon double fluorination, an unsymmetrical ethyl syn-2,5-difluoroalk-3-enoic ester was prepared, the silyl group acting as an anti stereodirecting group for the two C-F bond forming events.
Item Type: | Article |
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Status: | Published |
Schools: | Medicine |
Publisher: | Beilstein-Institut |
ISSN: | 1860-5397 |
Last Modified: | 04 Nov 2022 12:12 |
URI: | https://orca.cardiff.ac.uk/id/eprint/122223 |
Citation Data
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