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The quantization of theE ⊗ e Jahn–Teller Hamiltonian

Arvanitidis, Athanasios G., Vandaele, Eva R. J., Szopa, Marek and Ceulemans, Arnout 2017. The quantization of theE ⊗ e Jahn–Teller Hamiltonian. Journal of Physical Chemistry A 121 (38) , pp. 7246-7524. 10.1021/acs.jpca.7b06136

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The E ⊗ e Jahn–Teller Hamiltonian in the Bargmann–Fock representation gives rise to a system of two coupled first-order differential equations in the complex field, which may be rewritten in the Birkhoff standard form. General leapfrog recurrence relations are derived, from which the quantized solutions of these equations can be obtained. The results are compared to the analogous quantization scheme for the Rabi Hamiltonian.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: American Chemical Society
ISSN: 1089-5639
Last Modified: 14 Dec 2020 02:23

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