Preparation and catalytic properties of resin bound binuclear rhodium tetracarboxylate complexes

Andersen, Jo-Ann M., Karodia, Nazira, Miller, David James, Stones, Duane and Gani, David 1998. Preparation and catalytic properties of resin bound binuclear rhodium tetracarboxylate complexes. Tetrahedron Letters 39 (42) , pp. 7815-7818. 10.1016/S0040-4039(98)01709-2

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Abstract

-(4′-Polystyrylmethyloxy)-3-carboxylatomethyloxy-1-phenylacetate bis-μ-coordinated rhodium(II) diacetate complex, a resin-bound analogue of dirhodium tetraacetate in which two adjacent μ-bridging acetate moieties are covalently linked, serves as an efficient, stable and re-useable immobilised alkene hydrofomylation and hydrogenation catalyst. 4-(4′-Polystyrylmethyloxy)-3-carboxylatomethyloxy-1-phenylacetate bis-μ-coordinated rhodium(II) diacetate complex (3) serves as a polymer-supported catalyst for alkene hydroformylation and hydrogenation

Item Type:	Article
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Elsevier
ISSN:	0040-4039
Last Modified:	04 Jun 2017 02:49
URI:	https://orca.cardiff.ac.uk/id/eprint/12507

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