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Hydrogen bond structural group constants

Abraham, Michael H. and Platts, James Alexis ORCID: 2001. Hydrogen bond structural group constants. Journal of Organic Chemistry 66 (10) , pp. 3484-3491. 10.1021/jo001765s

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The ability of functional groups to act as hydrogen bond acids and bases can be obtained from either equilibrium constants for 1:1 hydrogen bonding or overall hydrogen bond constants. Either method leads to structural constants for hydrogen bonding that in some way are analogous to substituent constants. Extensive lists of these functional group constants are reported. It is shown that those derived from overall hydrogen bond constants are the more useful in analyses of physicochemical and biochemical properties.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: ACS
ISSN: 0022-3263
Last Modified: 18 Oct 2022 13:08

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