Synthesis, structural and theoretical studies of an iron-gallium(I) heterocycle complex: analogies with N-heterocyclic carbene chemistry

Baker, Robert James, Jones, Cameron James and Platts, James Alexis ORCID: https://orcid.org/0000-0002-1008-6595 2003. Synthesis, structural and theoretical studies of an iron-gallium(I) heterocycle complex: analogies with N-heterocyclic carbene chemistry. Dalton Transactions (19) , pp. 3673-3674. 10.1039/B308616J

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Abstract

The first iron complex of an anionic gallium N-heterocyclic carbene analogue, [Fe(CO)4{Ga[N(Ar)C(H)]2}]− Ar = C6H3Pri2-2,6, has been prepared and shown to have an unusual polymeric structure in the solid state; theoretical studies have pointed toward minimal Fe → Ga back-bonding in this complex.

Item Type:	Article
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	0300-9246
Last Modified:	18 Oct 2022 13:09
URI:	https://orca.cardiff.ac.uk/id/eprint/12523

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