1,1,2-Trimethylpropyldialkylcyanoborates as intermediates for the synthesis of symmetrical, unsymmetrical, functionalised, and cyclic ketones

Pelter, Andrew, Hutchings, M. G. and Smith, Keith ORCID: https://orcid.org/0000-0003-4838-5651 1971. 1,1,2-Trimethylpropyldialkylcyanoborates as intermediates for the synthesis of symmetrical, unsymmetrical, functionalised, and cyclic ketones. Journal of the Chemical Society. D, Chemical communications (18) , pp. 1048-1050. 10.1039/C29710001048

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Abstract

The insertion reaction of cyanide into hexyldialkylcyanoborates, using acylation at low temperatures followed by oxidation, provides the mildest known method for the high-yield production of ketones from olefins i in organoboranes.

Item Type:	Article
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	0009-241x
Last Modified:	04 Jun 2017 02:50
URI:	https://orca.cardiff.ac.uk/id/eprint/12573

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