Synthesis of secondary or tertiary alcohols by reactions of trialkylboranes with acyl carbanion equivalents

Hughes, Rosemary J., Ncube, Smollie, Pelter, Andrew, Smith, Keith, Negishi, Ei-ichi and Yoshida, Takao 1977. Synthesis of secondary or tertiary alcohols by reactions of trialkylboranes with acyl carbanion equivalents. Journal of the Chemical Society, Perkin Transactions 1 (10) , pp. 1172-1176. 10.1039/P19770001172

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Abstract

Reactions of trialkylboranes (R23B) with 1-lithio-1,1-bis(phenylthio)alkanes [R1(PhS)2C–Li+; R1= H or Prn], followed by reaction with mercury(II) chloride and oxidative work-up, give high yields of secondary (R1= H) or tertiary (R1= Prn) alcohols (R1R22COH).

Item Type:	Article
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	RSC Publishing
ISSN:	0300-922X
Last Modified:	04 Jun 2017 02:50
URI:	https://orca.cardiff.ac.uk/id/eprint/12613

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