Generation and reactions of 2-lithio-2-substituted-1,3-benzodithioles: new, convenient acyl carbanion equivalents

Ncube, S., Pelter, A., Smith, Keith, Blatcher, P. and Warren, S. 1978. Generation and reactions of 2-lithio-2-substituted-1,3-benzodithioles: new, convenient acyl carbanion equivalents. Tetrahedron Letters 19 (26) , pp. 2345-2348. 10.1016/S0040-4039(01)91532-1

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Abstract

The reaction ofBunLi with 2-substituted-1,3-benzodithioles yields anions which react predictably with organic electrophiles to yield products in which the protected carbonyl group is readily unmasked. The anions constitute useful acyl carbanion equivalents.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Elsevier
ISSN:	0040-4039
Last Modified:	04 Jun 2017 02:50
URI:	https://orca.cardiff.ac.uk/id/eprint/12626

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