The synthesis and some properties of the first boron-stabilized alkenyl carbanions

Pelter, A., Smith, Keith ORCID: https://orcid.org/0000-0003-4838-5651, Parry, D. E. and Jones, K. D. 1992. The synthesis and some properties of the first boron-stabilized alkenyl carbanions. Australian Journal of Chemistry 45 (1) , pp. 57-70. 10.1071/CH9920057

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Abstract

Calculations indicate a high degree of stabilization of H2BC=CH2 and that it has an allene -type structure H2B=C=CH2. Routes to boron-stabilized alkenyl carbanions have been established for the first time, and alkylation and protonation studies are described.

Item Type:	Article
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	CSIRO Publishing
ISSN:	0004-9425
Last Modified:	04 Jun 2017 02:51
URI:	https://orca.cardiff.ac.uk/id/eprint/12666

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