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A novel supported Katsuki-type (salen) Mn complex for asymmetric epoxidation

Smith, Keith, Liu, Chia-Hui and El-Hiti, Gamal A. 2006. A novel supported Katsuki-type (salen) Mn complex for asymmetric epoxidation. Organic & Biomolecular Chemistry 4 (5) , pp. 917-927. 10.1039/B517611P

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We have successfully prepared an unsymmetrical analogue of a Katsuki-type salen ligand having a hydroxyalkyl group at the 6-position of just one of the binaphthyl units in the ligand, and also several Mn(III) complexes; these complexes have been attached to a polymer by an ester link and such polymer catalysts have been shown to be highly enantioselective and recoverable catalysts for the epoxidation of 1,2-dihydronaphthalene.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1477-0520
Date of First Compliant Deposit: 30 March 2016
Last Modified: 13 May 2023 12:53

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