Alshahateet, Solhe F., Nakano, Kazunori, Bishop, Roger, Craig, Donald B., Harris, Kenneth David Maclean ![]() |
Abstract
The helical tubuland diol 4 forms 1∶1 hydrogen bonded co-crystalline adducts with 2-propanol and propanoic acid in space group P21/c, and with benzoic acid in C2/c. In the first of these compounds, the 2-propanol molecules contribute one hydroxy group to the intermolecular O–HO–HO–H hydrogen bond repeat unit. The co-crystals formed with propanoic acid and benzoic acid both contain a O–HOC(R)–O–HO–H repeat unit with the hydrogen bonds surrounding a pseudo-threefold screw axis, and where the carboxylic acid group functions like an extended alcohol hydroxy group. Aromatic offset face–face associations also play a significant role in the crystal structure of the benzoic acid compound.
Item Type: | Article |
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Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Publisher: | Royal Society of Chemistry |
ISSN: | 1466-8033 |
Last Modified: | 18 Oct 2022 13:10 |
URI: | https://orca.cardiff.ac.uk/id/eprint/12759 |
Citation Data
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