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Direct epitaxial synthesis of selective two-dimensional lateral heterostructures

Lee, Juwon, Pak, Sangyeon, Lee, Young-Woo, Park, Youngsin, Jang, A-Rang, Hong, John, Cho, Yuljae, Hou, Bo ORCID:, Lee, Sanghyo, Jeong, Hu Young, Shin, Hyeon Suk, Morris, Stephen M., Cha, SeungNam, Sohn, Jung Inn and Kim, Jong Min 2019. Direct epitaxial synthesis of selective two-dimensional lateral heterostructures. ACS Nano 13 (11) , pp. 13047-13055. 10.1021/acsnano.9b05722

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Two-dimensional (2D) heterostructured or alloyed monolayers composed of transition metal dichalcogenides (TMDCs) have recently emerged as promising materials with great potential for atomically thin electronic applications. However, fabrication of such artificial TMDC heterostructures with a sharp interface and a large crystal size still remains a challenge because of the difficulty in controlling various growth parameters simultaneously during the growth process. Here, a facile synthetic protocol designed for the production of the lateral TMDC heterostructured and alloyed monolayers is presented. A chemical vapor deposition approach combined with solution-processed precursor deposition makes it possible to accurately control the sequential introduction time and the supersaturation levels of the vaporized precursors and thus reliably and exclusively produces selective and heterogeneous epitaxial growth of TMDC monolayer crystals. In addition, TMDC core/shell heterostructured (MoS2/alloy, alloy/WS2) or alloyed (Mo1–xWxS2) monolayers are also easily obtained with precisely controlled growth parameters, such as sulfur introduction timing and growth temperature. These results represent a significant step toward the development of various 2D materials with interesting properties.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Physics and Astronomy
Publisher: American Chemical Society
ISSN: 1936-0851
Date of First Compliant Deposit: 24 February 2020
Date of Acceptance: 16 October 2019
Last Modified: 07 Nov 2023 07:02

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