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A high pressure investigation of the order-disorder phase transition and accompanying spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)

Shepherd, Helena, Tonge, George, Hatcher, Lauren, Bryant, Mathew, Knichal, Jane, Raithby, Paul, Halcrow, Malcolm, Kulmaczewski, Rafal, Gagnon, Kevin and Teat, Simon 2016. A high pressure investigation of the order-disorder phase transition and accompanying spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine). Magnetochemistry 2 (1) , -. 10.3390/magnetochemistry2010009

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Abstract

A high pressure single crystal X-ray diffraction and Raman spectroscopy study has revealed a similar mechanism for both thermal and pressure-induced spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) and the concomitant anion order-disorder transition.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
ISSN: 2312-7481
Date of First Compliant Deposit: 18 March 2020
Date of Acceptance: 2 February 2016
Last Modified: 19 Mar 2020 12:45
URI: https://orca.cardiff.ac.uk/id/eprint/130485

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