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Configurational selection in azobenzene-based supramolecular systems through dual-stimuli processes

Tecilla, Paolo and Bonifazi, Davide 2020. Configurational selection in azobenzene-based supramolecular systems through dual-stimuli processes. ChemistryOpen 9 (5) , pp. 538-553. 10.1002/open.202000045

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Azobenzene is one of the most studied light‐controlled molecular switches and it has been incorporated in a large variety of supramolecular systems to control their structural and functional properties. Given the peculiar isomeric distribution at the photoexcited state (PSS), azobenzene derivatives have been used as photoactive framework to build metastable supramolecular systems that are out of the thermodynamic equilibrium. This could be achieved exploiting the peculiar E/Z photoisomerization process that can lead to isomeric ratios that are unreachable in thermal equilibrium conditions. The challenge in the field is to find molecular architectures that, under given external circumstances, lead to a given isomeric ratio in a reversible and predictable manner, ensuring an ultimate control of the configurational distribution and system composition. By reviewing early and recent works in the field, this review aims at describing photoswitchable systems that, containing an azobenzene dye, display a controlled configurational equilibrium by means of a molecular recognition event. Specifically, examples include programmed photoactive molecular architectures binding cations, anions and H‐bonded neutral guests. In these systems the non‐covalent molecular recognition adds onto the thermal and light stimuli, equipping the supramolecular architecture with an additional external trigger to select the desired configuration composition.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Wiley
ISSN: 2191-1363
Funders: European Union
Date of First Compliant Deposit: 12 May 2020
Date of Acceptance: 30 March 2020
Last Modified: 13 May 2020 15:01

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