Direct bromination of keggin fragments to give [PW9O28Br6]3−: a polyoxotungstate with a hexabrominated face

Errington, John, Wingad, Richard, Clegg, William and Elsegood, Mark 2000. Direct bromination of keggin fragments to give [PW9O28Br6]3−: a polyoxotungstate with a hexabrominated face. Angewandte Chemie International Edition 39 (21) , pp. 3884-3886. 10.1002/1521-3773(20001103)39:21<3884::AID-ANIE3884>3.0.CO;2-M

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Abstract

Direct halogenations of polyoxometalates [NaPW11O39]6− and [PW9O34]9− led to [PW9O28Br6]3−, a molecular metal oxide with a fully brominated face (see picture). This methodology creates new opportunities for systematic chemistry at polyoxometalate surfaces.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Publisher:	Wiley
ISSN:	1433-7851
Date of Acceptance:	27 October 2000
Last Modified:	21 Jan 2021 12:00
URI:	https://orca.cardiff.ac.uk/id/eprint/137834

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