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Nickel-catalyzed decyanation of inert carbon–cyano bonds

Patra, Tuhin, Agasti, Soumitra, Akanksha and Maiti, Debabrata 2013. Nickel-catalyzed decyanation of inert carbon–cyano bonds. Chemical Communications 49 (1) , pp. 69-71. 10.1039/c2cc36883h

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Nickel catalyzed decyanation of aryl and aliphatic cyanides with hydrosilane as the hydride source has been developed. This method is easy to handle, scalable and can be carried out without a glove box. The method has been applied in the cyanide directed functionalization reaction and α-substitution of benzyl cyanide.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Date of Acceptance: 6 November 2012
Last Modified: 06 May 2023 01:58

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