Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Borane catalysed cyclopropenation of arylacetylenes

Stefkova, Katarina, Heard, Matthew J., Dasgupta, Ayan and Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831 2021. Borane catalysed cyclopropenation of arylacetylenes. Chemical Communications 57 (55) , pp. 6736-6739. 10.1039/D1CC01856F

[thumbnail of d1cc01856f.pdf]
Preview
PDF - Published Version
Available under License Creative Commons Attribution.

Download (3MB) | Preview

Abstract

Triarylboranes have gained substantial attention as catalysts for C–C bond forming reactions due to their remarkable catalytic activities. Herein, we report B(C6F5)3 catalysed cyclopropenation of a wide variety of arylacetylenes using donor–acceptor diazoesters. A mild reaction protocol has been developed for the synthesis of functionalised cyclopropenes (33 examples) in good to excellent yields.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Additional Information: This article is licensed under a Creative Commons Attribution 3.0 Unported Licence
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Funders: EPSRC
Date of First Compliant Deposit: 18 June 2021
Date of Acceptance: 7 June 2021
Last Modified: 09 Nov 2022 11:09
URI: https://orca.cardiff.ac.uk/id/eprint/141976

Citation Data

Cited 12 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item

Downloads

Downloads per month over past year

View more statistics