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Flow electrosynthesis of sulfoxides, sulfones, and sulfoximines without supporting electrolytes

Amri, Nasser and Wirth, Thomas 2021. Flow electrosynthesis of sulfoxides, sulfones, and sulfoximines without supporting electrolytes. Journal of Organic Chemistry 86 (22) , pp. 15961-15972. 10.1021/acs.joc.1c00860

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Abstract

An efficient electrochemical flow process for the selective oxidation of sulfides to sulfoxides and sulfones and of sulfoxides to N-cyanosulfoximines has been developed. In total, 69 examples of sulfoxides, sulfones, and N-cyanosulfoximines have been synthesized in good to excellent yields and with high current efficiencies. The synthesis was assisted and facilitated through a supporting electrolyte-free, fully automated electrochemical protocol highlighting the advantages of flow electrolysis.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: American Chemical Society
ISSN: 0022-3263
Date of First Compliant Deposit: 2 July 2021
Date of Acceptance: 10 June 2021
Last Modified: 25 Jun 2022 13:00
URI: https://orca.cardiff.ac.uk/id/eprint/142347

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