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Sonoelectrochemistry: ultrasound-assisted organic electrosynthesis

de Bitencourt Rodrigues, Higor, Oliveira de Brito Lira, Jéssica, Padoin, Natan, Soares, Cíntia, Qurashi, Ahsanulhaq and Ahmed, Nisar 2021. Sonoelectrochemistry: ultrasound-assisted organic electrosynthesis. ACS Sustainable Chemistry and Engineering 9 (29) , pp. 9590-9603. 10.1021/acssuschemeng.1c02989

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Abstract

The application of ultrasound with electrochemistry in organic chemistry (known as organic sonoelectrochemistry) accelerates the activation process of chemical reactions. This hybrid technology enhances electrical efficiency and modifies and increases the product yield. Moreover, it facilitates the mass transfer phenomena and the processes of cleaning, degassing, and activation of the electrode surfaces; maintains higher current densities for efficient chemical transformations; and also works efficiently for mixing of reactants in multiphase systems. The ultrasound technology has a prominent effect in heterogeneous reaction systems especially during the solid (electrode)–liquid (electrolytic mixture) interfacial cavitation process. The ultrasound technology gains attention due to its fundamental and positive effect in organic chemistry to make possible the challenging electrosynthetic processes. Herein, we report the sonoelectrosynthetic methods that will help researchers to understand and apply this methodology for scale-up of processes in organic synthesis and also in more modern innovative continuous-flow organic electrochemistry. Therefore, this study will provide valuable insight into the effects caused by ultrasound-assisted electrosynthesis and how this technology revolutionizes organic synthesis. It is believed that the hybrid sonoelectrochemical synthesis serves as a solution to the limitations of the commercialization of synthetic processes and offers a new, modern aspect in organic synthesis in a clean, hassle-free, and sustainable approach.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: American Chemical Society
ISSN: 2168-0485
Date of First Compliant Deposit: 15 July 2021
Date of Acceptance: 2 July 2021
Last Modified: 19 Jul 2022 04:29
URI: https://orca.cardiff.ac.uk/id/eprint/142611

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