Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Selectivity of the Lindlar catalyst in alkyne semi-hydrogenation: a direct liquid-phase adsorption study

Cherkasov, Nikolay, Murzin, Dmitry Yu., Catlow, C. Richard A. and Chutia, Arunabhiram 2021. Selectivity of the Lindlar catalyst in alkyne semi-hydrogenation: a direct liquid-phase adsorption study. Catalysis Science & Technology 11 (18) , pp. 6205-6216. 10.1039/D1CY01016F

[thumbnail of d1cy01016f.pdf] PDF - Published Version
Available under License Creative Commons Attribution.

Download (2MB)

Abstract

We study the alkyne semi-hydrogenation selectivity over Pd and Lindlar catalyst with liquid phase adsorption. The results indicate that there are strongly-adsorbing alkyne and alkene sites; alkenes react non-selectively over the alkene adsorption sites. DFT studies indicate that the non-selective sites are low-coordination Pd atoms in the nanoparticles.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Additional Information: his article is licensed under a Creative Commons Attribution 3.0 Unported Licence
Publisher: Royal Society of Chemistry
ISSN: 2044-4753
Funders: EPSRC and Royal Society
Date of First Compliant Deposit: 20 August 2021
Date of Acceptance: 16 July 2021
Last Modified: 14 Oct 2021 13:24
URI: https://orca.cardiff.ac.uk/id/eprint/143573

Citation Data

Cited 5 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item

Downloads

Downloads per month over past year

View more statistics