Novel synthesis of the monochloroborane–dimethyl sulphide complex via the reaction of borane–dimethyl sulphide with tetrachloromethane

Paget, Walter E. and Smith, Keith ORCID: https://orcid.org/0000-0003-4838-5651 1980. Novel synthesis of the monochloroborane–dimethyl sulphide complex via the reaction of borane–dimethyl sulphide with tetrachloromethane. Journal of the Chemical Society. Chemical communications (23) , pp. 1169-1170. 10.1039/C39800001169

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Abstract

Monochloroborane–dimethyl sulphide, BH2Cl.SMe2, is formed in essentially quantitative yield upon reflux of an equimolar mixture of borane–dimethyl sulphide, BH3.SMe2, and tetrachloromethane; it can be used directly for production of dialkylchloroboranes by the hydroboration of alkenes.

Item Type:	Article
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	0022-4936
Last Modified:	04 Jun 2017 02:57
URI:	https://orca.cardiff.ac.uk/id/eprint/14512

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