Highly para-selective mono-chlorination of aromatic compounds under mild conditions by t-Butyl hypochlorite in the presence of zeolites

Smith, Keith ORCID: https://orcid.org/0000-0003-4838-5651, Butters, Michael and Nay, Barry 1985. Highly para-selective mono-chlorination of aromatic compounds under mild conditions by t-Butyl hypochlorite in the presence of zeolites. Synthesis (Stuttgart) (12) , pp. 1157-1158. 10.1055/s-1985-31462

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Abstract

t-Butyl hypochlorite supported on H+, Na+ faujasite X (zeolite X) produces para-selective monchlorination of alkyl-, phenyl-, and halobenzenes under mild conditions; for example, chlorobenzene in acetonitrile (at 40°C) is chlorinated in high yield of isolated product (92%) to give dichlorobenzene with an isomer ratio 97% para/3% ortho.

Item Type:	Article
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Georg Thieme Verlag
ISSN:	0039-7881
Last Modified:	04 Jun 2017 02:57
URI:	https://orca.cardiff.ac.uk/id/eprint/14534

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