Smith, Keith, Butters, Michael and Nay, Barry 1985. Highly para-selective mono-chlorination of aromatic compounds under mild conditions by t-Butyl hypochlorite in the presence of zeolites. Synthesis (Stuttgart) (12) , pp. 1157-1158. 10.1055/s-1985-31462 |
Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Abstract
t-Butyl hypochlorite supported on H+, Na+ faujasite X (zeolite X) produces para-selective monchlorination of alkyl-, phenyl-, and halobenzenes under mild conditions; for example, chlorobenzene in acetonitrile (at 40°C) is chlorinated in high yield of isolated product (92%) to give dichlorobenzene with an isomer ratio 97% para/3% ortho.
Item Type: | Article |
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Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Publisher: | Georg Thieme Verlag |
ISSN: | 0039-7881 |
Last Modified: | 04 Jun 2017 02:57 |
URI: | https://orca.cardiff.ac.uk/id/eprint/14534 |
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