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An indenide-tethered N-heterocyclic stannylene

Bischof, Tobias, Evans, Kieren J. ORCID:, Haddow, Mairi F. and Mansell, Stephen M. 2020. An indenide-tethered N-heterocyclic stannylene. Acta Crystallographica Section E 76 (2) , pp. 254-256. 10.1107/S205698902000047X

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The structure of (μ-1κN:2(η2),κ2N,N′-(2-{[2,6-bis(propan-2-yl)phen­yl]aza­nid­yl}eth­yl)[2-(1H-inden-1-yl)eth­yl]aza­nido)(1,4,7,10,13,16-hexa­oxa­cyclo­octa­dec­ane-1κ6O)lithiumtin, [LiSn(C8H16O4)(C25H31N2)], at 100 K has monoclinic (P21/n) symmetry. Analysis of the coordination of the Sn to the indenyl ring shows that the Sn inter­acts in an η2 fashion. A database survey showed that whilst this coordination mode is unusual for Ge and Pb compounds, Sn displays a wider range of coordination modes to cyclo­penta­dienyl ligands and their derivatives.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Publisher: International Union of Crystallography
ISSN: 1600-5368
Date of First Compliant Deposit: 16 November 2021
Date of Acceptance: 14 January 2020
Last Modified: 10 Nov 2022 10:02

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