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Hypervalent bromine(III) compounds: synthesis, applications, prospects

Wirth, Thomas, Patra, Tuhin and Winterson, Bethan 2021. Hypervalent bromine(III) compounds: synthesis, applications, prospects. Synthesis: Journal of Synthetic Organic Chemistry 2021 (53) 10.1055/a-1675-8404

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Abstract

Hypervalent compounds play a prominent role in homogeneous oxidation catalysis. Despite the higher reactivity of hypervalent bromine compounds when compared to their isoelectronic iodine analogues, the corresponding λ3-bromanes are much less explored. This can be attributed to the discernible lack of convenient strategies for their synthesis. This short review highlights the available methods for the synthesis of various organo-λ3-bromanes, with a major focus on the recent developments and reactivities in the last few years. Additionally, limitations and future prospects of hypervalent bromine chemistry are discussed.

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Chemistry
Additional Information: This is an open access article published by Thieme under the terms of the Creative Commons Attribution License
Publisher: Thieme Gruppe
ISSN: 0039-7881
Funders: EPSRC
Date of First Compliant Deposit: 14 December 2021
Date of Acceptance: 21 October 2021
Last Modified: 17 Dec 2021 15:01
URI: https://orca.cardiff.ac.uk/id/eprint/146134

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