Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Single-reactor tandem oxidation–amination process for the synthesis of furan diamines from 5-hydroxymethylfurfural

Sha, Jin, Kusema, Bright T., Zhou, Wen-Juan, Yan, Zhen, Streiff, Stephane and Pera-Titus, Marc 2021. Single-reactor tandem oxidation–amination process for the synthesis of furan diamines from 5-hydroxymethylfurfural. Green Chemistry 23 (18) , pp. 7093-7099. 10.1039/D1GC01621K

Full text not available from this repository.

Abstract

We present an efficient and intensified single-reactor tandem process accessing a library of secondary furan diamines from HMF. The process comprises two in situ consecutive steps: (1) aerobic oxidation of HMF to DFF, and (2) reductive amination of DFF to diamines. The reactor was operated using a mechanical mixture of 5%Ru/C + 5%Pd/C catalysts with more than 87% overall yield of diamines. With these results, a bifunctional (Ru + Pd)/C catalyst was engineered with comparable results to the mechanical mixture. Graphical abstract: Single-reactor tandem oxidation–amination process for the synthesis of furan diamines from 5-hydroxymethylfurfural

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Publisher: Royal Society of Chemistry
ISSN: 1463-9262
Date of Acceptance: 16 August 2021
Last Modified: 21 Mar 2022 13:30
URI: https://orca.cardiff.ac.uk/id/eprint/148285

Citation Data

Cited 5 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item