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Tetrafluoro-IBA and -IBX: Hypervalent Iodine Reagents

Richardson, Robert David, Zayed, Jameel M., Altermann, Sabine, Smith, Daniel and Wirth, Thomas ORCID: 2007. Tetrafluoro-IBA and -IBX: Hypervalent Iodine Reagents. Angewandte Chemie - International Edition 46 (34) , pp. 6529-6532. 10.1002/anie.200702313

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Fluorine makes the difference: FIBX (see structure), the tetrafluoro derivative of the hypervalent iodine reagent, is more soluble and has higher reactivity than its nonfluorinated counterpart. An efficient synthesis of FIBX and initial reactions are presented. Some of these reactions can be conducted in standard organic solvents. Owing to the increased reactivity, new transformations and catalytic reactions may be possible.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: fluorine; hypervalent compounds; IBX; iodine; oxidation
Publisher: Wiley-Blackwell
ISSN: 1433-7851
Last Modified: 17 Oct 2022 08:56

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